Conjugate acids and bases

CONJUGATE ACIDS AND BASES

Every acid produces, a conjugate base and every base produces a conjugate acid, together forming a conjugate acid base pair. Conjugate means in pair.

Conjugate acid:

A specie formed by accepting a proton by a base.

Conjugate base:

A specie formed by donating a proton by an acid.

Explanation:

Forward and reverse reaction in acid-base equilibrium involves the proton transfer. Consider the following example

Conjugate acid and base example

In the forward reaction, the CH3COOH donates a proton to H2O. Therefore CH3COOH is a Bronsted-Lowry acid and H2O is a Bronsted-Lowry base.  In the reverse reaction CH3COO- accepts a proton from H3O+. Therefore CH3COO- is a base and H3O+ is an acid according to the Bronsted-Lowry concept.

Conjugate Acid-Base Pair:

An acid-base reaction consists of two species acid and base, they differ only by the loss or gain of a proton. The acid in such a pair is called conjugate acid of the base and the base in such a pair is called the conjugate base of the acid.

In the above example,
CH3COO- is a conjugate base of CH3COOH acid.
H3O+ is the conjugate acid of the H2O base.

NOTE:

  • A weak acid has a strong conjugate base.
  • A weak base has a strong conjugate acid.
  • A strong acid has a strong conjugate base.
  • A strong base has a weak conjugate acid.

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