Usanovish concept of acid and base

USANOVICH CONCEPT OF ACID AND BASE

USANOVICH CONCEPT OF ACID AND BASE

Usanovish in 1939 proposed a concept of acid and base and it was the most comprehensive concept.

Acids:

According to this concept, an acid is capable of 

  • combining with electrons
  • combining with anions
  • giving up cations

An acid is a cation, a cation donor, an electron pair acceptor, or an oxidant.

Bases:

According to this concept, a base is capable of

  • giving up anions
  • giving up electrons
  • combining with cations

An base is an anion, a cation acceptor, an electron-pair donor

For example:

\[SO_{3}\; +\; Na_{2}O\; \rightarrow Na_{2}SO_{4}\]
In the above example, Na2O gives an oxide ion so it is an acid and SO3 accepts this oxide ion so it is a base.

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